Chitosan-functionalized activated biochar from pomelo peel waste for methyl orange dye removal/
Nicole C. Agullo, Mitzi B. Laxamana, and Loiza Mae A. Panoy.--
- Manila: Technological University of the Philippines, 2025.
- xi, 93pages: 29cm.
Bachelor's thesis
College of Science.--
Includes bibliographic references and index.
This study aimed to develop chitosan-functionalized activated biochar (FPPAB) from pomelo peel waste for the removal of Methyl Orange (MO) dye from aqueous solutions. It sought to synthesize FPPAB through phosphoric acid activation, pyrolysis, and chitosan coating; evaluate its performance against unmodified and activated biochar; optimize key adsorption parameters; characterize the material; and identify the applicable adsorption kinetics and isotherm models. The biochar was characterized using FTIR, SEM, and EDX, confirming successful functionalization and surface modification. Batch adsorption experiments were conducted to assess the effects of contact time, initial concentration, pH, and temperature, with UV-Vis spectrophotometry used to measure dye removal. FPPAB achieved a maximum removal efficiency of 98.97% under optimal conditions: 0.1 g dosage, 25 minutes contact time, 90 ppm concentration, and pH 3 at 50°C. The process followed pseudo-second-order kinetics (R2 = 0.9999) and aligned with the Freundlich isotherm model (R2 = 0.8942). The findings highlight FPPAB as a promising, eco-friendly adsorbent for wastewater treatment.