000 03219nam a22003137a 4500
003 OSt
005 20250711141908.0
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040 _aTUPM
_bEnglish
_cTUPM
_dTUPM
_erda
050 _aBTH GF 41
_bB38 2025
100 _aBautista, Ethan Domini A.
_eauthor
245 _aGreen fabrication of paper-based chromium (vi) detector using sugarcane bagasse and tannin-crosslinked polyethyleneimine for water quality monitoring/
_cEthan Domini A. Bautista, Rochelle Ann V. Insigne, Marriane Angel A. Mandariaga, and Nathalie Joy M. Quezada.--
260 _aManila:
_bTechnological University of the Philippines,
_c2025.
300 _aviii, 133pages:
_c29cm.
336 _2rdacontent
337 _2rdamedia
338 _2rdacarrier
500 _aBachelor's thesis
502 _aCollege of Science.--
_bBachelor of science in environmental science:
_cTechnological University of the Philippines,
_d2025.
504 _aIncludes bibliographic references and index.
520 _aPreliminary water quality assessments identified chromium (Cr) as a significant contaminant in the Pasig River, emphasizing the need for continuous and real-time monitoring. However, current detection methods are costly, complex, and require technical expertise, limiting them to centralized laboratories. This study developed a low-cost,rapid, and portable method for selective Cr(VI) detection using sugarcane bagasse (SCB) and tannin-crosslinked polyethylenimine (TA-PEI) by using the color-changing complex instigated by the reduction of Cr(VI) in solutions as a colorimetric standard used to quantify chromium concentrations. After product optimization and comparison of methods, the colorimetric data collected from known Cr(VI) solutions yielded a strong linear regression with R2=0.9865 using the Eluate method, demonstrating a proportional relationship between blue channel intensity (IB) and Cr(VI) concentration. The selectivity of the chromogenic agent was also validated through tests with copper (Cu) and the organic pollutant nonylphenol, which showed no significant interference with Cr adsorption or the resulting color intensity changes. In field testing, the eluate method amounted to an estimated Cr concentration of 0.0724 ppm; while not yet validated for field deployment, the results provide a reliable foundation for laboratory simulations. Moreover, the PEI-TA- coated SCB showed excellent adsorption of Cr in lower concentrations, with a 76% Cr adsorption in 0.5 ppm solution and an adsorption capacity of 2.45 mg/g, all in consistent conditions and a pH value of 3. Additionally, the conducted community survey findings indicate that although awareness of environmental monitoring and stewardship is limited, residents are receptive to sustainable practices and open to adopting the detection method developed in the study.
650 _aSugarcane bagasse (SCB)
650 _aTannic acid-polyethyleneimine (TA-PEI)
650 _aColorimetric detection
700 _aInsigne, Rochelle Ann V.
_eauthor
700 _aMandariaga, Marriane Angel A.
_eauthor
700 _aQuezada, Nathalie Joy M.
_eauthor
942 _2lcc
_cBTH COS
_n0
999 _c30303
_d30303